Issue 5, 2003
From the journal:

Chemical Communications

A novel aggregate of [Mn2(μ-O)2] units: [Mn8O10(O2CMe)6(H2O)2(bpy)6]4+ with a serpentine core

Anastasios J. Tasiopoulos,a   Khalil A. Abbouda  and  George Christou*a  

* Corresponding authors

a Department of Chemistry, University of Florida, Gainesville, FL, USA
E-mail: christou@chem.ufl.edu
Fax: +1 352-392-8757
Tel: +1 352-392-8314

Abstract

The synthesis, characterization and initial reactivity studies are reported of the mixed-valence (MnIV6MnIII2) title compound, which possesses an unusual serpentine-like core and is the highest average oxidation state (+3.75) Mnx (x > 4) cluster to date.

Graphical abstract: A novel aggregate of [Mn2(μ-O)2] units: [Mn8O10(O2CMe)6(H2O)2(bpy)6]4+ with a serpentine core

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Article information

DOI
https://doi.org/10.1039/B211345G
Article type
Communication
Submitted
19 Nov 2002
Accepted
09 Jan 2003
First published
29 Jan 2003

Chem. Commun., 2003, 580-581

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A novel aggregate of [Mn2(μ-O)2] units: [Mn8O10(O2CMe)6(H2O)2(bpy)6]4+ with a serpentine core

A. J. Tasiopoulos, K. A. Abboud and G. Christou, Chem. Commun., 2003, 580 DOI: 10.1039/B211345G

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