Issue 7, 2003
From the journal:

Chemical Communications

A rapid and effective synthesis of propylene carbonate using a supercritical CO2–ionic liquid system

Hajime Kawanami,*ab   Akiyoshi Sasaki,a   Keitaro Matsuia  and  Yutaka Ikushima*ab  

* Corresponding authors

a Supercritical Fluid Research Center, National Institute of Advanced Industrial Science and Technology, 4-2-1 Nigatake, Miyagino-ku, Sendai 983-8551, Japan
E-mail: h-kawanami@aist.go.jp
Fax: +81-22-237-5215
Tel: +81-22-237-5211

b CREST, Japan Science and Technology Corporation (JST)

Abstract

The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.

Graphical abstract: A rapid and effective synthesis of propylene carbonate using a supercritical CO2–ionic liquid system

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B212823C
Article type
Communication
Submitted
17 Jan 2003
Accepted
14 Feb 2003
First published
07 Mar 2003

Chem. Commun., 2003, 896-897

Permissions

Request permissions

A rapid and effective synthesis of propylene carbonate using a supercritical CO2–ionic liquid system

H. Kawanami, A. Sasaki, K. Matsui and Y. Ikushima, Chem. Commun., 2003, 896 DOI: 10.1039/B212823C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements