Issue 7, 2003
From the journal:

Chemical Communications

Deuterium isotope effect on the solid-state thermal isomerization of photo-coloured cis-keto species of N-salicylideneaniline

Kiichi Amimoto,a   Hajime Kanatomi,a   Atsuyoshi Nagakari,a   Hisatane Fukuda,a   Hiroyuki Koyamaa  and  Toshio Kawato*a  

* Corresponding authors

a Department of Chemistry, Faculty of Sciences, Kyushu University, Ropponmatsu, Fukuoka 810-8560, Japan
E-mail: kawato@chem.rc.kyushu-u.ac.jp

Abstract

Deuterium isotope kinetic effect in the solid state was observed by using thermal fading reaction of photo-coloured species derived from N-salicylideneaniline deuterohydroxyl derivative; thus, the existence of a cis-keto form in the photo-coloured Schiff base crystals was suggested experimentally along with 6-methyl-substitution effect on the stability of the photoproduct.

Graphical abstract: Deuterium isotope effect on the solid-state thermal isomerization of photo-coloured cis-keto species of N-salicylideneaniline

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Article information

DOI
https://doi.org/10.1039/B300830D
Article type
Communication
Submitted
21 Jan 2003
Accepted
20 Feb 2003
First published
05 Mar 2003

Chem. Commun., 2003, 870-871

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Deuterium isotope effect on the solid-state thermal isomerization of photo-coloured cis-keto species of N-salicylideneaniline

K. Amimoto, H. Kanatomi, A. Nagakari, H. Fukuda, H. Koyama and T. Kawato, Chem. Commun., 2003, 870 DOI: 10.1039/B300830D

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