Issue 12, 2003
From the journal:

Chemical Communications

The preparation of hexasilsesquioxane (T6) cages by “non aqueous” hydrolysis of trichlorosilanes

Alan R. Bassindale,*a   Iain A. MacKinnon,b   Maria G. Maesanoa  and  Peter G. Taylor*a  

* Corresponding authors

a The Chemistry Department, The Open University, Walton Hall, Milton Keynes, UK
E-mail: P.G.Taylor@open.ac.uk
Fax: (+44) 1908 858327
Tel: (+44) 1908 652512

b Dow Corning Ltd, Cardiff Road, Barry, South Glamorgan, UK

Abstract

Hexasilsesquioxane cages (T6) have been prepared from a range of alkyl and aryl trichlorosilanes using a “non aqueous” hydrolysis with dimethyl sulfoxide.

Graphical abstract: The preparation of hexasilsesquioxane (T6) cages by “non aqueous” hydrolysis of trichlorosilanes

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Article information

DOI
https://doi.org/10.1039/B302556J
Article type
Communication
Submitted
06 Mar 2003
Accepted
15 Apr 2003
First published
13 May 2003

Chem. Commun., 2003, 1382-1383

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The preparation of hexasilsesquioxane (T6) cages by “non aqueous” hydrolysis of trichlorosilanes

A. R. Bassindale, I. A. MacKinnon, M. G. Maesano and P. G. Taylor, Chem. Commun., 2003, 1382 DOI: 10.1039/B302556J

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