Issue 16, 2003
From the journal:

Chemical Communications

Pinwheel motifs: formation of unusual homo- and hetero-nuclear aggregates via bridging thiolates†

Angelo J. Amoroso,a   Simon S. M. Chung,a   Douglas J. E. Spencer,a   Jonathan P. Danks,a   Mark W. Glenny,a   Alexander J. Blake,a   Paul A. Cooke,a   Claire Wilsona  and  Martin Schröder*a  

* Corresponding authors

a School of Chemistry, The University of Nottingham, Nottingham, UK

Abstract

The homohexanuclear complexes [Ni2{Ni(L1)}4](BF4)4·MeCN, 1, [Pd2{Pd(L2)}4](BF4)4, 2, and the heteropentanuclear aggregate [Cu2{Ni(L3)}3](PF6)2, 3, all adopt a ‘pinwheel’ type structural motif via thiolate bridging between square-planar Ni(II) or Pd(II) and between trigonal planar Cu(I) centres, respectively.

Graphical abstract: Pinwheel motifs: formation of unusual homo- and hetero-nuclear aggregates via bridging thiolates

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Article information

DOI
https://doi.org/10.1039/B303851C
Article type
Communication
Submitted
07 Apr 2003
Accepted
30 May 2003
First published
02 Jul 2003

Chem. Commun., 2003, 2020-2021

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Pinwheel motifs: formation of unusual homo- and hetero-nuclear aggregates via bridging thiolates

A. J. Amoroso, S. S. M. Chung, D. J. E. Spencer, J. P. Danks, M. W. Glenny, A. J. Blake, P. A. Cooke, C. Wilson and M. Schröder, Chem. Commun., 2003, 2020 DOI: 10.1039/B303851C

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