cis-1,5-Diaminocyclooctane: the most basic gaseous primary amine?
Abstract
The gas phase basicity of the title compound has been determined to be greater than that of putrescine, making it the most basic primary diamine measured to date.
* Corresponding authors
a
Department of Chemistry, The College of William and Mary, Williamsburg, VA, USA
E-mail:
jcpout@wm.edu
Fax: 1 (757) 221-2715
Tel: (757) 221-2548
b
Department of Chemistry, University of California, Riverside, CA, USA
E-mail:
morton@citrus.ucr.edu
Fax: 1 (909) 787-4713
Tel: 1 (909) 787-4735
The gas phase basicity of the title compound has been determined to be greater than that of putrescine, making it the most basic primary diamine measured to date.
J. C. Poutsma, E. J. Andriole, T. Sissung and T. H. Morton, Chem. Commun., 2003, 2040 DOI: 10.1039/B305239G
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