Issue 21, 2003

Thermodynamically controlled cyclisation reactions with double phenylsulfanyl migration

Abstract

Enantiomerically enriched C2-symmetric tetrols were synthesised by a route involving a ‘self-metathesis’ reaction with Grubbs' second-generation ruthenium catalyst; these tetrols produced interesting bicyclic products when rearranged under acidic conditions.

Graphical abstract: Thermodynamically controlled cyclisation reactions with double phenylsulfanyl migration

Supplementary files

Article information

Article type
Communication
Submitted
23 Jul 2003
Accepted
05 Sep 2003
First published
30 Sep 2003

Chem. Commun., 2003, 2696-2697

Thermodynamically controlled cyclisation reactions with double phenylsulfanyl migration

J. Carlisle, D. J. Fox and S. Warren, Chem. Commun., 2003, 2696 DOI: 10.1039/B308609G

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