Issue 21, 2003
From the journal:

Chemical Communications

Insertion of pyridine into an iron–silicon bond: structure of the product Cp*(CO)Fe{η3(C,C,C)-C5H5NSiMe2NPh2}†

Masatoshi Iwata,a   Masaaki Okazaki*a  and  Hiromi Tobita*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
E-mail: mokazaki@mail.tains.tohoku.ac.jp (MO), tobita@mail.tains.tohoku.ac.jp (HT)
Fax: 81-22-217-6543
Tel: 81-22-217-6539

Abstract

Heating a toluene solution of Cp*(CO)(C5H5N)FeSiMe2NPh2 led to insertion of pyridine into the iron–silicon bond to form Cp*(CO)Fe{η3(C,C,C)-C5H5NSiMe2NPh2}.

Graphical abstract: Insertion of pyridine into an iron–silicon bond: structure of the product Cp*(CO)Fe{η3(C,C,C)-C5H5NSiMe2NPh2}

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Article information

DOI
https://doi.org/10.1039/B308885E
Article type
Communication
Submitted
29 Jul 2003
Accepted
17 Sep 2003
First published
08 Oct 2003

Chem. Commun., 2003, 2744-2745

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Insertion of pyridine into an iron–silicon bond: structure of the product Cp*(CO)Fe{η3(C,C,C)-C5H5NSiMe2NPh2}

M. Iwata, M. Okazaki and H. Tobita, Chem. Commun., 2003, 2744 DOI: 10.1039/B308885E

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