Issue 7, 2003
From the journal:

Dalton Transactions

A highly oxidized Re27+ species with an electron-poor bond of order 3.5

John F. Berry,a   F. Albert Cotton,*a   Penglin Huanga  and  Carlos A. Murillo*a  

* Corresponding authors

a Department of Chemistry and Laboratory for Molecular Structure and Bonding, PO Box 30012 Texas A&M University, College Station, Texas 77842-3012, USA
E-mail: cotton@tamu.edu (F.A.C.); murillo@tamu.edu (C.A.M.)

Abstract

The first paddlewheel complex with an Re27+ core and an electron-poor bond order of 3.5 is paramagnetic and shows a metal–metal bond lengthening of 0.035 Å relative to the corresponding compound having a quadruple bond and an Re26+ core.

Graphical abstract: A highly oxidized Re27+ species with an electron-poor bond of order 3.5

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Article information

DOI
https://doi.org/10.1039/B301360J
Article type
Communication
Submitted
04 Feb 2003
Accepted
24 Feb 2003
First published
04 Mar 2003

Dalton Trans., 2003, 1218-1219

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A highly oxidized Re27+ species with an electron-poor bond of order 3.5

J. F. Berry, F. Albert Cotton, P. Huang and C. A. Murillo, Dalton Trans., 2003, 1218 DOI: 10.1039/B301360J

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