Issue 14, 2003
From the journal:

Dalton Transactions

Novel palladium and platinum carbene-complexes containing dithiocarbonate ligand [M(PPh3){η2(S,S)-S2CO]{C(SR)(NMe2)}] formed viaalkyl migration of O-alkyldithiocarbonate to thiocarbamoyl ligand†

Kuang-Hway Yih,*a   Gene-Hsiang Leeb  and  Yu Wangc  

* Corresponding authors

a Department of Applied Cosmetology, Hungkuang University, Shalu, Taichung, Republic of China

b Instrumentation Center, College of Science, National Taiwan University, Taiwan, Republic of China

c Department of Chemistry, National Taiwan University, Taiwan 106, Republic of China

Abstract

The first example of alkyl migration of O-alkyldithiocarbonate to thiocarbamoyl ligand results in carbene-complexes [M(PPh3){η2(S,S)-S2CO]{C(SR)(NMe2)}] (M = Pd, Pt; R = Me, Et) from the reactions of [M(η2-SCNMe2)(PPh3)2][PF6] with KS2COR in MeOH.

Graphical abstract: Novel palladium and platinum carbene-complexes containing dithiocarbonate ligand [M(PPh3){η2(S,S)-S2CO]{C(SR)(NMe2)}] formed via alkyl migration of O-alkyldithiocarbonate to thiocarbamoyl ligand

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Article information

DOI
https://doi.org/10.1039/B305374A
Article type
Communication
Submitted
13 May 2003
Accepted
18 Jun 2003
First published
24 Jun 2003

Dalton Trans., 2003, 2810-2812

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Novel palladium and platinum carbene-complexes containing dithiocarbonate ligand [M(PPh3){η2(S,S)-S2CO]{C(SR)(NMe2)}] formed via alkyl migration of O-alkyldithiocarbonate to thiocarbamoyl ligand

K. Yih, G. Lee and Y. Wang, Dalton Trans., 2003, 2810 DOI: 10.1039/B305374A

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