Issue 7, 2003
From the journal:

Organic & Biomolecular Chemistry

Does the DABCO-catalysed reaction of 2-hydroxybenzaldehydes with methyl acrylate follow a Baylis–Hillman pathway?

Perry T. Kaye,*a   Musiliyu A. Musa,a   Xolani W. Nocandaa  and  Ross S. Robinsona  

* Corresponding authors

a Department of Chemistry, Rhodes University, Grahamstown, 6140, South Africa
E-mail: P.Kaye@ru.ac.za

Abstract

Evidence is presented which supports the intermediacy of dipolar Baylis–Hillman-type adducts in the synthesis of coumarin and chromene derivatives from the reaction of 2-hydroxybenzaldehydes with methyl acrylate in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO).

Graphical abstract: Does the DABCO-catalysed reaction of 2-hydroxybenzaldehydes with methyl acrylate follow a Baylis–Hillman pathway?

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Article information

DOI
https://doi.org/10.1039/B300360D
Article type
Paper
Submitted
15 Jan 2003
Accepted
13 Feb 2003
First published
10 Mar 2003

Org. Biomol. Chem., 2003,1, 1133-1138

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Does the DABCO-catalysed reaction of 2-hydroxybenzaldehydes with methyl acrylate follow a Baylis–Hillman pathway?

P. T. Kaye, M. A. Musa, X. W. Nocanda and R. S. Robinson, Org. Biomol. Chem., 2003, 1, 1133 DOI: 10.1039/B300360D

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