Issue 4, 2004
From the journal:

Chemical Communications

Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

Piyush Shukla,a   Jennifer A. Johnson,a   Dragoslav Vidovic,a   Alan H. Cowleya  and  Colin D. Abernethyb  

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712, USA
E-mail: cowley@mail.utexas.edu
Fax: 512-471-7484

b Department of Chemistry, Western Kentucky University, Bowling Green, KY 42101, USA

Abstract

The reaction of 1,3-dimesitylimidazolium chloride with Ti(NMe2)4 results in the 1,3-dimesitylimadazol-2-ylidene complex of Ti(NMe2)2Cl2 (3); the X-ray crystal structure of 3 evidences short intramolecular Cl⋯Ccarbene contacts.

Graphical abstract: Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

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Article information

DOI
https://doi.org/10.1039/B314558A
Article type
Communication
Submitted
13 Nov 2003
Accepted
27 Nov 2003
First published
15 Jan 2004

Chem. Commun., 2004, 360-361

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Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

P. Shukla, J. A. Johnson, D. Vidovic, A. H. Cowley and C. D. Abernethy, Chem. Commun., 2004, 360 DOI: 10.1039/B314558A

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