Issue 10, 2004
From the journal:

Chemical Communications

A new (63)·(69.81) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical†

Daniel Maspoch,a   Daniel Ruiz-Molina,a   Klaus Wurst,b   Concepció Roviraa  and  Jaume Veciana*a  

* Corresponding authors

a Institut de Ciència de Materials de Barcelona (CSIC), Campus Universitari, Catalonia, 08193 Bellaterra, Spain
E-mail: vecianaj@icmab.es
Fax: 34 93 5805729
Tel: 34 93 580 1853

b Institut für Allgemeine Anorganische und Theoretische Chemie, Universität Innsbruck, Innrain 52a, A-6020, Austria

Abstract

The reaction of a 3-connecting PTMTC radical and a 2-connecting 4,4′-bipyridine ligands with Co(MeCOO)2·4H2O forms a paramagnetic non-interpenetrated supramolecular network, Co(PTMTC)(4,4′-bpy)(H2O)3·6EtOH·2H2O (MOROF-2), with an unprecedented (63)·(69.81) topology exhibiting helical nanochannels.

Graphical abstract: A new (63)·(69.81) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical

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Article information

DOI
https://doi.org/10.1039/B315147F
Article type
Communication
Submitted
24 Nov 2003
Accepted
31 Mar 2004
First published
22 Apr 2004

Chem. Commun., 2004, 1164-1165

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A new (63)·(69.81) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical

D. Maspoch, D. Ruiz-Molina, K. Wurst, C. Rovira and J. Veciana, Chem. Commun., 2004, 1164 DOI: 10.1039/B315147F

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