Issue 7, 2004
From the journal:

Chemical Communications

Palladium-catalyzed reaction of 4-cyclopentene-1,3-diol monoacetate with Grignard reagents producing hitherto unreachable cis-1,2-isomers†

Hatsuhiko Hattori,a   Ashraf A. Abbasab  and  Yuichi Kobayashi*a  

* Corresponding authors

a Department of Biomolecular Engineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8501, Japan
E-mail: ykobayas@bio.titech.ac.jp
Fax: +81-45-924-5789
Tel: +81-45-924-5789

b Department of Chemistry, Faculty of Science, Cairo University, Giza, Egypt

Abstract

Reaction of 4-cyclopentene-1,3-diol monoacetate with RMgCl (R = alkyl, aryl) in the presence of a palladium catalyst proceeded with retention of configuration to give cis-1,2-regioisomers as the major products.

Graphical abstract: Palladium-catalyzed reaction of 4-cyclopentene-1,3-diol monoacetate with Grignard reagents producing hitherto unreachable cis-1,2-isomers

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Article information

DOI
https://doi.org/10.1039/B316596E
Article type
Communication
Submitted
22 Dec 2003
Accepted
18 Feb 2004
First published
05 Mar 2004

Chem. Commun., 2004, 884-885

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Palladium-catalyzed reaction of 4-cyclopentene-1,3-diol monoacetate with Grignard reagents producing hitherto unreachable cis-1,2-isomers

H. Hattori, A. A. Abbas and Y. Kobayashi, Chem. Commun., 2004, 884 DOI: 10.1039/B316596E

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