Issue 12, 2004
From the journal:

Chemical Communications

Synthesis and characterization of the hexagonal prismatic cage {THF⊂[PhB(CN)3]6[Cp*Rh]6}6+†

Matthew L. Kuhlman,a   Haijun Yaoa  and  Thomas B. Rauchfuss*a  

* Corresponding authors

a Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL, 6180, USA
E-mail: rauchfuz@uiuc.edu

Abstract

Condensation of [Cp*Rh(CH3NO2)n]2+ and the tricyanoborate [PhB(CN)3]− affords the hexagonal bipyramidal cage {[PhB(CN)3]6[Cp*Rh]6}6+, demonstrating that tetrahedral tricyanide building blocks can lead to novel cage structures.

Graphical abstract: Synthesis and characterization of the hexagonal prismatic cage {THF⊂[PhB(CN)3]6[Cp*Rh]6}6+

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Article information

DOI
https://doi.org/10.1039/B401505C
Article type
Communication
Submitted
02 Feb 2004
Accepted
29 Apr 2004
First published
18 May 2004

Chem. Commun., 2004, 1370-1371

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Synthesis and characterization of the hexagonal prismatic cage {THF⊂[PhB(CN)3]6[Cp*Rh]6}6+

M. L. Kuhlman, H. Yao and T. B. Rauchfuss, Chem. Commun., 2004, 1370 DOI: 10.1039/B401505C

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