Issue 10, 2004
From the journal:

Chemical Communications

Programmed single step self-assembly of a [2 × 2] grid architecture built on metallic centers of different coordination geometries

Anne Petitjean,†a   Nathalie Kyritsakasb  and  Jean-Marie Lehn*a  

* Corresponding authors

a Laboratoire de Chimie Supramoléculaire, ISIS ULP, 8 allée Gaspard Monge, BP 70028, F-67083 Strasbourg Cedex, France
E-mail: lehn@isis.strasbg.fr

b Service Commun de Rayons X, 4 rue Blaise Pascal, F-67070 Strasbourg Cedex, France

Abstract

A novel type of 2 × 2 grid type architecture incorporating two ions of different geometries results from the single step directed self-assembly of a bischelating ligand combining bridged bidentate and tridentate complexation subunits, designed so as to lead to the ion selective and toposelective introduction of two Zn(II) and two Cu(I) cations at well-defined, diagonally located positions of, respectively, octahedral and tetrahedral coordination geometry.

Graphical abstract: Programmed single step self-assembly of a [2 × 2] grid architecture built on metallic centers of different coordination geometries

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Article information

DOI
https://doi.org/10.1039/B402854F
Article type
Communication
Submitted
26 Feb 2004
Accepted
02 Apr 2004
First published
23 Apr 2004

Chem. Commun., 2004, 1168-1169

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Programmed single step self-assembly of a [2 × 2] grid architecture built on metallic centers of different coordination geometries

A. Petitjean, N. Kyritsakas and J. Lehn, Chem. Commun., 2004, 1168 DOI: 10.1039/B402854F

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