Issue 11, 2004
From the journal:

Chemical Communications

Ruthenium/chloride catalytic system for conjugate addition of terminal alkynes to acrylate esters

Takahiro Nishimura,*a   Yosuke Washitake,a   Yoshiki Nishiguchi,a   Yasunari Maedaa  and  Sakae Uemura*a  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: uemura@scl.kyoto-u.ac.jp
Fax: +81 75 383 2517
Tel: +81 75 383 2517

Abstract

The addition of terminal alkynes to acrylate esters in the presence of a ruthenium catalyst and chloride sources proceeds to give the corresponding γ,δ-alkynyl esters in good yields.

Graphical abstract: Ruthenium/chloride catalytic system for conjugate addition of terminal alkynes to acrylate esters

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Article information

DOI
https://doi.org/10.1039/B403616F
Article type
Communication
Submitted
10 Mar 2004
Accepted
13 Apr 2004
First published
10 May 2004

Chem. Commun., 2004, 1312-1313

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Ruthenium/chloride catalytic system for conjugate addition of terminal alkynes to acrylate esters

T. Nishimura, Y. Washitake, Y. Nishiguchi, Y. Maeda and S. Uemura, Chem. Commun., 2004, 1312 DOI: 10.1039/B403616F

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