Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn12 core: a route to the controlled functionalisation of single-molecule magnets

Mirko Pacchioni; Andrea Cornia; Antonio C. Fabretti; Laura Zobbi; Daniele Bonacchi; Andrea Caneschi; Guillaume Chastanet; Dante Gatteschi; Roberta Sessoli

doi:10.1039/B411320A

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Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn₁₂ core: a route to the controlled functionalisation of single-molecule magnets†

Mirko Pacchioni,^ab Andrea Cornia,*^a Antonio C. Fabretti,^a Laura Zobbi,^a Daniele Bonacchi,^b Andrea Caneschi,^b Guillaume Chastanet,^b Dante Gatteschi^b and Roberta Sessoli*^b

Author affiliations

* Corresponding authors

^a Dipartimento di Chimica, INSTM and Università di Modena e Reggio Emilia, via G. Campi 183, Modena, Italy
E-mail: acornia@unimore.it
Fax: +39-59-373543
Tel: +39-59-2055032

^b Dipartimento di Chimica, INSTM and Università di Firenze, via della Lastruccia 3, Sesto Fiorentino, Italy
E-mail: roberta.sessoli@unifi.it
Fax: +39-55-4573372
Tel: +39-55-4573268

Abstract

A novel single-molecule magnet of the Mn₁₂ family, [Mn₁₂O₁₂(O₂CC₆H₅)₈(L)₄(H₂O)₄]·8CH₂Cl₂, has been synthesised by site-specific ligand exchange using a tailor-made dicarboxylate (L²⁻), which leads to selective occupation of axial binding sites.

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Article information

DOI: https://doi.org/10.1039/B411320A
Article type: Communication
Submitted: 26 Jul 2004
Accepted: 24 Aug 2004
First published: 01 Oct 2004

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Chem. Commun., 2004, 2604-2605

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Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn₁₂ core: a route to the controlled functionalisation of single-molecule magnets

M. Pacchioni, A. Cornia, A. C. Fabretti, L. Zobbi, D. Bonacchi, A. Caneschi, G. Chastanet, D. Gatteschi and R. Sessoli, Chem. Commun., 2004, 2604 DOI: 10.1039/B411320A

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