Issue 4, 2005

Coupling of alkynols and a phenyl group to a novel η5-dihydronaphthalenide ligand on a ruthenium template

Abstract

We report the highly selective assembly of unprecedented η5-1-methylene-1,2-dihydronaphthalenide ligands from the stoichiometric coupling of a phenyl group and two equivalents of disubstituted propargylic alcohols; in this reaction, tetraphenylborate acts as a phenylating agent.

Graphical abstract: Coupling of alkynols and a phenyl group to a novel η5-dihydronaphthalenide ligand on a ruthenium template

Supplementary files

Article information

Article type
Communication
Submitted
05 Aug 2004
Accepted
23 Sep 2004
First published
02 Dec 2004

Chem. Commun., 2005, 510-512

Coupling of alkynols and a phenyl group to a novel η5-dihydronaphthalenide ligand on a ruthenium template

J. Čubrilo, R. F. Winter and D. Gudat, Chem. Commun., 2005, 510 DOI: 10.1039/B412052C

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