Issue 4, 2005
From the journal:

Chemical Communications

A luminescent linear trinuclear magnesium complex assembled from a phosphorus-based tris-hydrazone ligand†

Vadapalli Chandrasekhar,*a   Ramachandran Azhakar,a   Jamie F. Bickleyb  and  Alexander Steinerb  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology-Kanpur, Kanpur 208016, India
E-mail: vc@iitk.ac.in
Fax: +91-512-2590007/2597436

b Department of Chemistry, University of Liverpool, Liverpool, UK

Abstract

A novel linear trinuclear magnesium complex {P(S)[N(CH3)N[double bond, length as m-dash]CHC6H4-o-O]3}2Mg3 was prepared by the reaction of P(S)[N(CH3)N[double bond, length as m-dash]CHC6H4-o-OH]3 with MgCl2·6H2O in the presence of triethylamine. The trinuclear magnesium complex is fluorescent in solution as well as in the solid-state.

Graphical abstract: A luminescent linear trinuclear magnesium complex assembled from a phosphorus-based tris-hydrazone ligand

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Article information

DOI
https://doi.org/10.1039/B414353A
Article type
Communication
Submitted
07 Sep 2004
Accepted
11 Oct 2004
First published
06 Dec 2004

Chem. Commun., 2005, 459-461

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A luminescent linear trinuclear magnesium complex assembled from a phosphorus-based tris-hydrazone ligand

V. Chandrasekhar, R. Azhakar, J. F. Bickley and A. Steiner, Chem. Commun., 2005, 459 DOI: 10.1039/B414353A

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