Issue 14, 2005
From the journal:

Chemical Communications

Novel poly(methimazolyl)borate complexes of niobium(v) and tantalum(v)

Anthony F. Hill*a  and  Matthew K. Smitha  

* Corresponding authors

a Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, A.C.T., Australia
E-mail: a.hill@anu.edu.au
Fax: (+61) 2 6125 3216
Tel: (+61) 2 6125 8577

Abstract

The reactions of [MCl4(η-C5H5)] (M = Nb, Ta) with Ph3Sn{HB(mt)3} (mt = methimazolyl) provide structurally characterised complexes of the new chlorobis(methimazolyl)borate ligand, [MCl3(η-C5H5){κ2-S,S′-HClB(mt)2}].

Graphical abstract: Novel poly(methimazolyl)borate complexes of niobium(v) and tantalum(v)

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Article information

DOI
https://doi.org/10.1039/B415852K
Article type
Communication
Submitted
14 Oct 2004
Accepted
16 Dec 2004
First published
09 Feb 2005

Chem. Commun., 2005, 1920-1922

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Novel poly(methimazolyl)borate complexes of niobium(V) and tantalum(V)

A. F. Hill and M. K. Smith, Chem. Commun., 2005, 1920 DOI: 10.1039/B415852K

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