Issue 35, 2005
From the journal:

Chemical Communications

Superparamagnetic nanoparticle-supported enzymatic resolution of racemic carboxylates†

Hari M. R. Gardimalla,a   Deendayal Mandal,a   Philip D. Stevens,a   Max Yenb  and  Yong Gao*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Mailcode 4409, Southern Illinois University, Carbondale, USA
E-mail: ygao@chem.siu.edu
Tel: +1 (618)453-4904

b Materials Technology Center, Southern Illinois University, ENGR A-120, Carbondale, USA

Abstract

Candida rugosa lipase immobilized on maghemite nanoparticles demonstrated high stereoselectivity in kinetic resolution of racemic carboxylates and improved long-term stability over its parent free enzyme, allowing the supported enzyme to be repeatedly used for a series of chiral resolution reactions.

Graphical abstract: Superparamagnetic nanoparticle-supported enzymatic resolution of racemic carboxylates

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Article information

DOI
https://doi.org/10.1039/B504128G
Article type
Communication
Submitted
21 Mar 2005
Accepted
12 Jul 2005
First published
11 Aug 2005

Chem. Commun., 2005, 4432-4434

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Superparamagnetic nanoparticle-supported enzymatic resolution of racemic carboxylates

H. M. R. Gardimalla, D. Mandal, P. D. Stevens, M. Yen and Y. Gao, Chem. Commun., 2005, 4432 DOI: 10.1039/B504128G

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