Catalytic C–C bond cleavage and C–Si bond formation in the reaction of RCN with Et3SiH promoted by an iron complex

Hiroshi Nakazawa; Kouji Kamata; Masumi Itazaki

doi:10.1039/B504131G

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Catalytic C–C bond cleavage and C–Si bond formation in the reaction of RCN with Et₃SiH promoted by an iron complex†

Hiroshi Nakazawa,*^a Kouji Kamata^a and Masumi Itazaki^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan
E-mail: nakazawa@sci.osaka-cu.ac.jp
Fax: +81-6-6605-2522
Tel: +81-6-6605-3123

Abstract

Catalytic C–C bond cleavage of acetonitrile and C–Si bond formation have been attained in the photoreaction of MeCN with Et₃SiH in the presence of an iron complex, Cp(CO)₂FeMe. This catalytic system can be applied for arylnitrile C–C bond cleavage.

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Article information

DOI: https://doi.org/10.1039/B504131G
Article type: Communication
Submitted: 23 Mar 2005
Accepted: 13 Jun 2005
First published: 12 Jul 2005

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Chem. Commun., 2005, 4004-4006

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Catalytic C–C bond cleavage and C–Si bond formation in the reaction of RCN with Et₃SiH promoted by an iron complex

H. Nakazawa, K. Kamata and M. Itazaki, Chem. Commun., 2005, 4004 DOI: 10.1039/B504131G

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