Issue 32, 2005
From the journal:

Chemical Communications

Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction†

Isamu Shiina,*a   Yo-ichi Kawakita,a   Ryoutarou Ibuka,a   Kazutoshi Yokoyamaa  and  Yu-suke Yamaia  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Japan
E-mail: shiina@ch.kagu.tus.ac.jp
Fax: (+81)-3-3260-5609

Abstract

An efficient method for the synthesis of (+)-buergerinin F is established via the enantioselective aldol reaction of a tetrasubstituted ketene silyl acetal with crotonaldehyde, followed by intramolecular Wacker-type ketalization.

Graphical abstract: Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

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Article information

DOI
https://doi.org/10.1039/B507401K
Article type
Communication
Submitted
26 May 2005
Accepted
17 Jun 2005
First published
14 Jul 2005

Chem. Commun., 2005, 4062-4064

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Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

I. Shiina, Y. Kawakita, R. Ibuka, K. Yokoyama and Y. Yamai, Chem. Commun., 2005, 4062 DOI: 10.1039/B507401K

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