Issue 38, 2005
From the journal:

Chemical Communications

Ring-opening polymerisation of coordination compounds: a silver(i) network with both ring and polymer components

Nancy L. S. Yue,a   Michael C. Jenningsa  and  Richard J. Puddephatt*a  

* Corresponding authors

a Department of Chemistry, University of Western Ontario, London, Canada
E-mail: pudd@uwo.ca
Fax: +1 519-661-3022

Abstract

The terpyridyl ligand 2,6-C5H3N{C([double bond, length as m-dash]O)N(Me)-4-C5H4N}2, 1, combined with silver(I) salts to give the complexes [Ag2(1)2][BF4]2, 2, and [{Ag3(1)2}n][CF3SO3]3n, 3; the network structure of complex 3 contains both macrocyclic units [Ag2(μ-1)2]2+ and ring-opened polymeric units [{Ag(μ-1)}n]n+.

Graphical abstract: Ring-opening polymerisation of coordination compounds: a silver(i) network with both ring and polymer components

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Article information

DOI
https://doi.org/10.1039/B510080A
Article type
Communication
Submitted
15 Jul 2005
Accepted
05 Aug 2005
First published
31 Aug 2005

Chem. Commun., 2005, 4792-4794

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Ring-opening polymerisation of coordination compounds: a silver(I) network with both ring and polymer components

N. L. S. Yue, M. C. Jennings and R. J. Puddephatt, Chem. Commun., 2005, 4792 DOI: 10.1039/B510080A

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