[Ba2(H2O)9][GeSe4] is suitable for the formation of novel M/14/16 anions [Mn6Ge4Se17]6−—discrete or linked in an as yet unprecedented porous network—with antiferromagnetically coupled MnII centers and relatively small electronic excitation energies.
![Graphical abstract: Ternary Mn/Ge/Se anions from reactions of [Ba2(H2O)9][GeSe4]: Synthesis and characterization of compounds containing discrete or polymeric [Mn6Ge4Se17]6− units](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=B513305J&imageInfo.ImageIdentifier.Year=2005)
M. Melullis, R. Clérac and S. Dehnen, Chem. Commun., 2005, 6008 DOI: 10.1039/B513305J
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