Issue 48, 2005
From the journal:

Chemical Communications

Crystal-to-crystal transformation from tri- to mononuclear Cu(ii) complex with a sugar-derived ligandvia proton transfer reaction and rearrangement of hydrogen bonding networks†

Ajay K. Saha  and  Tomoaki Tanase*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-higashi-machi, Nara, Japan
E-mail: tanase@cc.nara-wu.ac.jp
Fax: +81 742 203399
Tel: +81 742 203399

Abstract

Treatment of a glycosylamine derived Cu(II) complex with ethylamine resulted in crystal-to-crystal transformation from trinuclear complex [Cu3(L1)2(EtNH2)2(MeOH)2]·2MeOH·CHCl3 (2·2MeOH·CHCl3) to a dimeric structure of mononuclear complex [Cu(HL1)(EtNH2)] (3) through proton transfer reaction and rearrangement of hydrogen bonding networks.

Graphical abstract: Crystal-to-crystal transformation from tri- to mononuclear Cu(ii) complex with a sugar-derived ligand via proton transfer reaction and rearrangement of hydrogen bonding networks

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Article information

DOI
https://doi.org/10.1039/B513788H
Article type
Communication
Submitted
29 Sep 2005
Accepted
24 Oct 2005
First published
11 Nov 2005

Chem. Commun., 2005, 5980-5981

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Crystal-to-crystal transformation from tri- to mononuclear Cu(II) complex with a sugar-derived ligand via proton transfer reaction and rearrangement of hydrogen bonding networks

A. K. Sah and T. Tanase, Chem. Commun., 2005, 5980 DOI: 10.1039/B513788H

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