Issue 2, 2006
From the journal:

Chemical Communications

Unusual carbon–sulfur bond cleavage in the reaction of a new type of bulky hexathioether with a zerovalent palladium complex†

Daisuke Shimizu,a   Nobuhiro Takedaa  and  Norihiro Tokitoh*a  

* Corresponding authors

a Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto, Japan
E-mail: tokitoh@boc.kuicr.kyoto-u.ac.jp
Fax: +81 774 38 3209
Tel: +81 774 38 3200

Abstract

The reaction of a bulky hexathioether, TbtS(o-Phen)S(o-Phen)SS(o-Phen)S(o-Phen)STbt (o-Phen = o-phenylene, Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl) (1), with 3 molar amounts of Pd(PPh3)4 afforded trinuclear palladium complex 4 bridged by two benzenedithiolato ligands via a three-step palladium insertion reaction into one sulfur–sulfur and two carbon–sulfur bonds of 1.

Graphical abstract: Unusual carbon–sulfur bond cleavage in the reaction of a new type of bulky hexathioether with a zerovalent palladium complex

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Article information

DOI
https://doi.org/10.1039/B513339D
Article type
Communication
Submitted
21 Sep 2005
Accepted
21 Oct 2005
First published
21 Nov 2005

Chem. Commun., 2006, 177-179

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Unusual carbon–sulfur bond cleavage in the reaction of a new type of bulky hexathioether with a zerovalent palladium complex

D. Shimizu, N. Takeda and N. Tokitoh, Chem. Commun., 2006, 177 DOI: 10.1039/B513339D

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