Issue 21, 2006

Base-catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a dimeric chiral diamidobinaphthyl dilithium salt

Abstract

A dimeric proline derived diamidobinaphthyl dilithium salt represents the first example of a chiral main group metal based catalyst for asymmetric hydroamination/cyclisation reactions of aminoalkenes.

Graphical abstract: Base-catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a dimeric chiral diamidobinaphthyl dilithium salt

Supplementary files

Article information

Article type
Communication
Submitted
03 Jan 2006
Accepted
28 Mar 2006
First published
11 Apr 2006

Chem. Commun., 2006, 2221-2223

Base-catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a dimeric chiral diamidobinaphthyl dilithium salt

P. H. Martínez, K. C. Hultzsch and F. Hampel, Chem. Commun., 2006, 2221 DOI: 10.1039/B518360J

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