Issue 20, 2006
From the journal:

Chemical Communications

Copolymerisation of Pt–carbonyl clusters with Lewis acids: synthesis and crystal structure of the molecular {Cd2Cl4[Pt9(CO)18]2−}∞ 1-D polymer

Cristina Femoni,a   Francesco Kaswalder,a   Maria Carmela Iapalucci,a   Giuliano Longoni*a  and  Stefano Zacchinia  

* Corresponding authors

a Dipartimento di Chimica Fisica ed Inorganica, Università di Bologna, viale Risorgimento 4, Italy
E-mail: longoni@ms.fci.unibo.it
Fax: (+39) 051 209 3690
Tel: (+39) 051 209 3697

Abstract

Reaction of [NBu4]2[Pt9(CO)18] with the soft Lewis acid CdCl2 gives the [Pt9(CO)18(μ3-CdCl2)2]2− adduct, which self-assembles upon crystallization into a 1-D {[Pt9(CO)18(μ3-CdCl2)2]2−}∞ polymer via the formation of chloride bridges.

Graphical abstract: Copolymerisation of Pt–carbonyl clusters with Lewis acids: synthesis and crystal structure of the molecular {Cd2Cl4[Pt9(CO)18]2−}∞ 1-D polymer

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Article information

DOI
https://doi.org/10.1039/B602593E
Article type
Communication
Submitted
21 Feb 2006
Accepted
28 Mar 2006
First published
12 Apr 2006

Chem. Commun., 2006, 2135-2137

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Copolymerisation of Pt–carbonyl clusters with Lewis acids: synthesis and crystal structure of the molecular {Cd2Cl4[Pt9(CO)18]2−}∞ 1-D polymer

C. Femoni, F. Kaswalder, M. C. Iapalucci, G. Longoni and S. Zacchini, Chem. Commun., 2006, 2135 DOI: 10.1039/B602593E

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