Issue 20, 2006
From the journal:

Chemical Communications

Relative importance of X⋯O[double bond, length as m-dash]C vs. X⋯X halogen bonding as structural determinants in 4-halotriaroylbenzenes†

F. Christopher Pigge,*a   Venu R. Vangalaa  and  Dale C. Swensona  

* Corresponding authors

a Department of Chemistry, University of Iowa, Iowa City, Iowa, USA
E-mail: chris-pigge@uiowa.edu
Fax: 319-335-1270
Tel: 319-335-3805

Abstract

The structures of 4-chloro- and 4-bromotribenzoylbenzene, as well as a solid solution prepared from these two components, are isomorphous and dominated by C–X⋯O[double bond, length as m-dash]C interactions, whereas type-II I⋯I interactions are important in the 4-iodo derivative.

Graphical abstract: Relative importance of X⋯O [[double bond, length as m-dash]] C vs. X⋯X halogen bonding as structural determinants in 4-halotriaroylbenzenes

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Article information

DOI
https://doi.org/10.1039/B603110B
Article type
Communication
Submitted
02 Mar 2006
Accepted
31 Mar 2006
First published
20 Apr 2006

Chem. Commun., 2006, 2123-2125

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Relative importance of X⋯O[double bond, length as m-dash]C vs. X⋯X halogen bonding as structural determinants in 4-halotriaroylbenzenes

F. C. Pigge, V. R. Vangala and D. C. Swenson, Chem. Commun., 2006, 2123 DOI: 10.1039/B603110B

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