Issue 21, 2006
From the journal:

Chemical Communications

Selective aerobic oxidation in supercritical carbon dioxide catalyzed by the H5PV2Mo10O40 polyoxometalate†

Galia Maayan,a   Benjamin Ganchegui,b   Walter Leitner*bc  and  Ronny Neumann*a  

* Corresponding authors

a Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel
E-mail: Ronny.Neumann@weizmann.ac.il
Fax: +972-(0)8-9343354
Tel: +972-(0)8-9343354

b Institut für Technische und Makromolekulare Chemie, Worringerweg 1, RWTH Aachen, Aachen, Germany
E-mail: leitner@itmc.rwth-aachen.de
Fax: +49-(0)241-8022177
Tel: +49-(0)241-8026480

c Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, Mülheim an der Ruhr, Germany
E-mail: leitner@itmc.rwth-aachen.de

Abstract

Selective aerobic oxidation of benzylic alcohols and of activated aromatic hydrocarbons occurs in supercritical CO2 as reaction medium using H5PV2Mo10O40 as a quasi-heterogeneous catalyst without further additives or co-solvents; efficient recycling is possible and no metal leaching is detectable in the product stream.

Graphical abstract: Selective aerobic oxidation in supercritical carbon dioxide catalyzed by the H5PV2Mo10O40 polyoxometalate

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Article information

DOI
https://doi.org/10.1039/B603148J
Article type
Communication
Submitted
02 Mar 2006
Accepted
04 Apr 2006
First published
25 Apr 2006

Chem. Commun., 2006, 2230-2232

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Selective aerobic oxidation in supercritical carbon dioxide catalyzed by the H5PV2Mo10O40 polyoxometalate

G. Maayan, B. Ganchegui, W. Leitner and R. Neumann, Chem. Commun., 2006, 2230 DOI: 10.1039/B603148J

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