A star-shaped ruthenium complex with five ferrocenyl-terminated arms bridged by trans-platinum fragments†
Abstract
We present the synthesis of the new heteropolytopic penta(4-ethynylphenyl)cyclopentadiene ligand, its complexation through the Cp ring to ruthenium tris(indazolyl)borate and through the terminal alkyne groups to five ferrocenyl ethynyl platinum units, yielding an undecanuclear heterotrimetallic complex.