Issue 24, 2006
From the journal:

Chemical Communications

Migratory insertion of [B(C6F5)2] into C–H bonds: CO promoted transfer of the boryl fragment†

Simon Aldridge,*a   Deborah L. Kays (née Coombs),‡a   Amal Al-Fawaz,a   Kevin M. Jones,a   Peter N. Horton,b   Michael B. Hursthouse,b   Ross W. Harringtonc  and  William Cleggc  

* Corresponding authors

a Centre for Fundamental and Applied Main Group Chemistry, Cardiff School of Chemistry, Main Building, Park Place, Cardiff, UK
E-mail: AldridgeS@cf.ac.uk
Fax: 02920 874030
Tel: 02920 875495

b EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, UK

c School of Natural Sciences (Chemistry), Bedson Building, University of Newcastle, Newcatle-upon-Tyne, UK

Abstract

The reaction of (η5-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C–H insertion) to the Cp ring, thereby generating the zwitterion [η5-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield.

Graphical abstract: Migratory insertion of [B(C6F5)2] into C–H bonds: CO promoted transfer of the boryl fragment

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Article information

DOI
https://doi.org/10.1039/B604141H
Article type
Communication
Submitted
21 Mar 2006
Accepted
21 Apr 2006
First published
10 May 2006

Chem. Commun., 2006, 2578-2580

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Migratory insertion of [B(C6F5)2] into C–H bonds: CO promoted transfer of the boryl fragment

S. Aldridge, D. L. Kays (née Coombs), A. Al-Fawaz, K. M. Jones, P. N. Horton, M. B. Hursthouse, R. W. Harrington and W. Clegg, Chem. Commun., 2006, 2578 DOI: 10.1039/B604141H

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