Issue 25, 2006
From the journal:

Chemical Communications

Reactivity of electrophilic μ-phosphinidene complexes with N-heterocyclic carbenes: formation of the first main group element adducts of ‘abnormal’ carbene ligands†

Todd W. Graham,ab   Konstantin A. Udachina  and  Arthur J. Carty*ab  

* Corresponding authors

a Steacie Institute for Molecular Sciences, National Research Council of Canada, 100 Sussex Drive, Ottawa, Canada

b The Ottawa-Carleton Chemistry Institute, University of Ottawa, Ottawa, Canada
E-mail: acarty@pco-bcp.gc.ca
Fax: +1 613 948 6667
Tel: +1 613 948 6672

Abstract

The reactions of Mn2- and Co2-containing μ-PNiPr2 complexes with NCN carbenes afford the ‘abnormal’ carbene adducts [Mn2(CO)8{μ-P(NiPr2)}(4-cyclo-C3H2-1,3-(NR)2))] and [Co2(CO)4(μ-dppm){μ-P(NiPr2)(4-cyclo-C3H2-1,3-(NR)2)}] (R = tBu, adamantyl), respectively.

Graphical abstract: Reactivity of electrophilic μ-phosphinidene complexes with N-heterocyclic carbenes: formation of the first main group element adducts of ‘abnormal’ carbene ligands

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Article information

DOI
https://doi.org/10.1039/B604150G
Article type
Communication
Submitted
21 Mar 2006
Accepted
25 Apr 2006
First published
18 May 2006

Chem. Commun., 2006, 2699-2701

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Reactivity of electrophilic μ-phosphinidene complexes with N-heterocyclic carbenes: formation of the first main group element adducts of ‘abnormal’ carbene ligands

T. W. Graham, K. A. Udachin and A. J. Carty, Chem. Commun., 2006, 2699 DOI: 10.1039/B604150G

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