Issue 24, 2006
From the journal:

Chemical Communications

A high-nuclearity, beyond “fully reduced” polyoxo(alkoxo)vanadium(iii/iv) cage

Ian S. Tidmarsh,a   Rebecca H. Laye,a   Paul R. Brearley,a   Maheswaran Shanmugam,a   E. Carolina Sañudo,a   Lorenzo Sorace,b   Andrea Caneschib  and  Eric J. L. McInnes*a  

* Corresponding authors

a School of Chemistry, The University of Manchester, Manchester, UK
E-mail: eric.mcinnes@manchester.ac.uk
Fax: +44-(0)161-275-4616
Tel: +44-161-275-4469

b Department of Chemistry, Poloscientifico, Florence, Italy

Abstract

The solvothermal synthesis, crystal structure and preliminary magnetic studies are reported of the first high nuclearity VIII-based polyoxo(alkoxo)vanadium cage, a VIII16VIV2 complex.

Graphical abstract: A high-nuclearity, beyond “fully reduced” polyoxo(alkoxo)vanadium(iii/iv) cage

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Article information

DOI
https://doi.org/10.1039/B605106E
Article type
Communication
Submitted
10 Apr 2006
Accepted
04 May 2006
First published
18 May 2006

Chem. Commun., 2006, 2560-2562

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A high-nuclearity, beyond “fully reduced” polyoxo(alkoxo)vanadium(III/IV) cage

I. S. Tidmarsh, R. H. Laye, P. R. Brearley, M. Shanmugam, E. C. Sañudo, L. Sorace, A. Caneschi and E. J. L. McInnes, Chem. Commun., 2006, 2560 DOI: 10.1039/B605106E

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