Depending upon the nature of the substituent at the β-position of the sulfoxide moiety, a Pummerer reaction can be oriented “at will” towards Cα–H (rearrangement) or Cα–Cβ (fragmentation) bond cleavage.
B. Laleu, M. S. Machado and J. Lacour, Chem. Commun., 2006, 2786 DOI: 10.1039/B605187A
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