Issue 35, 2006
From the journal:

Chemical Communications

The self-assembly between C2-symmetric (methanol)6 or S6-symmetric (ethanol)6 cyclohexamers and paddle-wheel dinuclear copper units leads to unique 1D polymer chains†

Laurent Benisvy,a   Ilpo Mutikainen,b   Manuel Quesada,a   Urho Turpeinen,b   Patrick Gameza  and  Jan Reedijk*a  

* Corresponding authors

a Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, RA Leiden, The Netherlands
E-mail: reedijk@chem.leidenuniv.nl
Fax: 31 715274671

b Department of Chemistry, Laboratory of Inorganic Chemistry, University of Helsinki, PO Box 55, A. I. Virtasenaukio 1, Helsinki, Finland

Abstract

The first crystallographic evidences of the theoretically suggested C2-symmetric cyclohexameric form of liquid methanol and the S6-symmetric cyclohexameric form of liquid ethanol are reported, trapped inside a hydrophilic pocket shielded by tert-butyl groups.

Graphical abstract: The self-assembly between C2-symmetric (methanol)6 or S6-symmetric (ethanol)6 cyclohexamers and paddle-wheel dinuclear copper units leads to unique 1D polymer chains

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Article information

DOI
https://doi.org/10.1039/B608220C
Article type
Communication
Submitted
09 Jun 2006
Accepted
03 Jul 2006
First published
31 Jul 2006

Chem. Commun., 2006, 3723-3725

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The self-assembly between C2-symmetric (methanol)6 or S6-symmetric (ethanol)6 cyclohexamers and paddle-wheel dinuclear copper units leads to unique 1D polymer chains

L. Benisvy, I. Mutikainen, M. Quesada, U. Turpeinen, P. Gamez and J. Reedijk, Chem. Commun., 2006, 3723 DOI: 10.1039/B608220C

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