Issue 10, 2007
From the journal:

Chemical Communications

Actinide-mediated coupling of 4-fluorobenzonitrile: synthesis of an eight-membered thorium(iv) tetraazametallacycle†

Eric J. Schelter,a   David E. Morris,a   Brian L. Scotta  and  Jaqueline L. Kiplinger*a  

* Corresponding authors

a Los Alamos National Laboratory, Los Alamos, USA
E-mail: kiplinger@lanl.gov
Fax: +1 505-667-9905
Tel: +1 505-665-9553

Abstract

An eight-membered thorium(IV) tetraazamacrocycle is produced by the sequential, metal-mediated coupling of four equivalents of 4-fluorobenzonitrile; its formation is consistent with the involvement of an imido intermediate, generated from a thorium ketimide complex.

Graphical abstract: Actinide-mediated coupling of 4-fluorobenzonitrile: synthesis of an eight-membered thorium(iv) tetraazametallacycle

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Article information

DOI
https://doi.org/10.1039/B614050E
Article type
Communication
Submitted
29 Sep 2006
Accepted
20 Nov 2006
First published
03 Jan 2007

Chem. Commun., 2007, 1029-1031

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Actinide-mediated coupling of 4-fluorobenzonitrile: synthesis of an eight-membered thorium(IV) tetraazametallacycle

E. J. Schelter, D. E. Morris, B. L. Scott and J. L. Kiplinger, Chem. Commun., 2007, 1029 DOI: 10.1039/B614050E

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