Issue 13, 2007
From the journal:

Chemical Communications

A NADPH substitute for selective photo-initiation of reductive bioprocesses via two-photon induced electron transfer†

Anne-Claire Robin,a   Said Gmouh,a   Olivier Mongin,a   Viatcheslav Jouikov,a   Martinus H. V. Werts,a   Clément Gautier,b   Anny Slama-Schwokb  and  Mireille Blanchard-Desce*a  

* Corresponding authors

a Synthèse et Electrosynthèse Organiques (CNRS, UMR 6510), Université de Rennes 1, Campus Scientifique de Beaulieu, Bât. 10A, Rennes Cedex, France
E-mail: mireille.blanchard-desce@univ-rennes1.fr
Fax: (+33) 2 23 23 62 77
Tel: (+33) 2 23 23 62 77

b Laboratoire Optique et Biosciences (INSERM U696), Ecole Polytechnique, Palaiseau, France

Abstract

A NADPH substitute where the nicotinamide moiety is replaced by a chromophoric unit having much larger two-photon absorption cross-section and able to transfer electrons to flavins only upon excitation is described as an effective two-photon nanotrigger for selective photo-activation of electron transfer in bioreductive processes.

Graphical abstract: A NADPH substitute for selective photo-initiation of reductive bioprocesses via two-photon induced electron transfer

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Article information

DOI
https://doi.org/10.1039/B615628B
Article type
Communication
Submitted
27 Oct 2006
Accepted
21 Dec 2006
First published
18 Jan 2007

Chem. Commun., 2007, 1334-1336

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A NADPH substitute for selective photo-initiation of reductive bioprocesses via two-photon induced electron transfer

A. Robin, S. Gmouh, O. Mongin, V. Jouikov, M. H. V. Werts, C. Gautier, A. Slama-Schwok and M. Blanchard-Desce, Chem. Commun., 2007, 1334 DOI: 10.1039/B615628B

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