Issue 14, 2007
From the journal:

Chemical Communications

Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(i) nitrate reveal cooperativity properties in porous molecular materials†

Partha S. Mukherjee,a   Nazario Lopez,b   Atta M. Arif,c   Francisco Cervantes-Leeb  and  Juan C. Noveron*b  

* Corresponding authors

a Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, India

b Department of Chemistry, University of Texas at El Paso, El Paso, TX, USA
E-mail: jcnoveron@utep.edu
Fax: (915)747-5748
Tel: (915) 747-7572

c Department of Chemistry, University of Utah, Salt Lake City, UT, USA

Abstract

Two single-crystal to single-crystal phase transitions in trans-[Ag(NPI)2](NO3)·2CH3OH (1a), (NPI = N-phenylisonicotinamide) were characterized with X-ray crystallography; the first transition is reversible and arises from a desolvation transition induced by vacuum and generated 1b; the second transition was induced by heat at 140 °C and generated 1c.

Graphical abstract: Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(i) nitrate reveal cooperativity properties in porous molecular materials

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Article information

DOI
https://doi.org/10.1039/B616502H
Article type
Communication
Submitted
13 Nov 2006
Accepted
09 Jan 2007
First published
30 Jan 2007

Chem. Commun., 2007, 1433-1435

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Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(I) nitrate reveal cooperativity properties in porous molecular materials

P. S. Mukherjee, N. Lopez, A. M. Arif, F. Cervantes-Lee and J. C. Noveron, Chem. Commun., 2007, 1433 DOI: 10.1039/B616502H

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