Issue 10, 2007
From the journal:

Chemical Communications

Monomeric, two-coordinate Mn, Fe and Co(ii) complexes featuring 2,6-(2,4,6-trimethylphenyl)phenyl ligands†

Deborah L. Kays (née Coombs)*a  and  Andrew R. Cowleya  

* Corresponding authors

a Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, UK
E-mail: Deborah.Kays@chem.ox.ac.uk
Fax: 01865 285002
Tel: 01865 285137

Abstract

The synthesis and characterization of the monomeric, two-coordinate transition-metal complexes (2,6-Mes2C6H3)2M (Mes = mesityl, 2,4,6-Me3C6H2, M = Mn, Fe, Co) are reported; (2,6-Mes2C6H3)2Co is the first structurally authenticated two-coordinate, homoleptic cobalt(II) complex featuring σ-bonded aryl ligands.

Graphical abstract: Monomeric, two-coordinate Mn, Fe and Co(ii) complexes featuring 2,6-(2,4,6-trimethylphenyl)phenyl ligands

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Article information

DOI
https://doi.org/10.1039/B616584B
Article type
Communication
Submitted
15 Nov 2006
Accepted
15 Jan 2007
First published
02 Feb 2007

Chem. Commun., 2007, 1053-1055

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Monomeric, two-coordinate Mn, Fe and Co(II) complexes featuring 2,6-(2,4,6-trimethylphenyl)phenyl ligands

D. L. Kays (née Coombs) and A. R. Cowley, Chem. Commun., 2007, 1053 DOI: 10.1039/B616584B

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