Advancements in natural abundance solid-state 33S MAS NMR: characterization of transition-metal MS bonds in ammonium tetrathiometallates

Hans J. Jakobsen; Anders R. Hove; Henrik Bildsøe; Jørgen Skibsted; Michael Brorson

doi:10.1039/B618497A

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Advancements in natural abundance solid-state ³³S MAS NMR: characterization of transition-metal MS bonds in ammonium tetrathiometallates†

Hans J. Jakobsen,*^a Anders R. Hove,^a Henrik Bildsøe,^a Jørgen Skibsted^a and Michael Brorson^b

Author affiliations

* Corresponding authors

^a Instrument Centre for Solid-State NMR Spectroscopy, Department of Chemistry, University of Aarhus, Aarhus C, Denmark
E-mail: hja@chem.au.dk
Fax: +45 8619 6199
Tel: +45 8942 3842

^b Haldor Topsøe A/S, Nymøllevej 55, Lyngby, Denmark
E-mail: mib@topsoe.dk
Fax: +45 4527 2999
Tel: +45 4527 2653

Abstract

We report the first ³³S chemical shift anisotropy (CSA) data as obtained from a combined determination of ³³S CSA and quadrupole coupling parameters utilizing the observation of both the ³³S (I = 3/2) central and satellite transitions in a natural abundance ³³S MAS NMR study aimed at characterizing the two important tetrathiometallates (NH₄)₂MoS₄ and (NH₄)₂WS₄.

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Supplementary files

Experimental details. Synthesis and ³³S MAS NMR spectroscopy of (NH ₄) ₂MS ₄ (M = Mo, W) PDF (136K)

Article information

DOI: https://doi.org/10.1039/B618497A
Article type: Communication
Submitted: 19 Dec 2006
Accepted: 12 Jan 2007
First published: 06 Feb 2007

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Chem. Commun., 2007, 1629-1631

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Advancements in natural abundance solid-state ³³S MAS NMR: characterization of transition-metal MS bonds in ammonium tetrathiometallates

H. J. Jakobsen, A. R. Hove, H. Bildsøe, J. Skibsted and M. Brorson, Chem. Commun., 2007, 1629 DOI: 10.1039/B618497A

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