Issue 29, 2007
From the journal:

Chemical Communications

Synthesis of the entire carbon framework of the kedarcidin chromophore aglycon†

Fumihiko Yoshimura,a   Martin J. Lear,*ab   Isao Ohashi,a   Yasuhito Koyamaa  and  Masahiro Hirama*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
E-mail: hirama@mail.tains.tohoku.ac.jp
Fax: +81-22-795-6566

b Department of Chemistry, and Medicinal Chemistry Programme, 3 Science Drive 3, National University of Singapore, Republic of Singapore 117543
E-mail: chmlmj@nus.edu.sg
Fax: +65-6779-1691

Abstract

In advanced studies directed toward the total synthesis of the kedarcidin chromophore, we have successfully achieved the late-stage installation of the nine-membered diyne ring in the presence of the highly functionalised ansamacrocyclic bridge.

Graphical abstract: Synthesis of the entire carbon framework of the kedarcidin chromophore aglycon

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Article information

DOI
https://doi.org/10.1039/B705932A
Article type
Communication
Submitted
19 Apr 2007
Accepted
20 Jun 2007
First published
29 Jun 2007

Chem. Commun., 2007, 3057-3059

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Synthesis of the entire carbon framework of the kedarcidin chromophore aglycon

F. Yoshimura, M. J. Lear, I. Ohashi, Y. Koyama and M. Hirama, Chem. Commun., 2007, 3057 DOI: 10.1039/B705932A

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