Issue 29, 2007
From the journal:

Chemical Communications

Homochiral H-bonded proline based metal organic frameworks†

Michael J. Ingleson,a   John Bacsaa  and  Matthew J. Rosseinsky*a  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Liverpool, UK
E-mail: m.j.rosseinsky@liv.ac.uk
Fax: (+44) 151 794 3598
Tel: (+44) 151 794 3504

Abstract

Two L-proline based homochiral frameworks synthesised via diffusion and solvothermal methods display distinct L-proline bonding modes, one N,O chelating and one O,O bridging with amine nitrogen not bound to the metal, with binding mode dependent upon the degree of protonation of the amino acid.

Graphical abstract: Homochiral H-bonded proline based metal organic frameworks

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Article information

DOI
https://doi.org/10.1039/B706557D
Article type
Communication
Submitted
01 May 2007
Accepted
07 Jun 2007
First published
27 Jun 2007

Chem. Commun., 2007, 3036-3038

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Homochiral H-bonded proline based metal organic frameworks

M. J. Ingleson, J. Bacsa and M. J. Rosseinsky, Chem. Commun., 2007, 3036 DOI: 10.1039/B706557D

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