An unprecedented nanoporous and fluorescent supramolecular framework with an SrAl2 topology controllably synthesized from a flexible ditopic acid

Su-Na Wang; Yong Yang; Junfeng Bai; Yi-Zhi Li; Manfred Scheer; Yi Pan; Xiao-Zeng You

doi:10.1039/B710389A

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An unprecedented nanoporous and fluorescent supramolecular framework with an SrAl₂ topology controllably synthesized from a flexible ditopic acid†

Su-Na Wang,^a Yong Yang,^a Junfeng Bai,*^a Yi-Zhi Li,^a Manfred Scheer,^b Yi Pan*^a and Xiao-Zeng You^a

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, P. R. China
E-mail: bjunfeng@nju.edu.cn
Fax: + 86 25-8331-4502

^b Institut für Anorganische Chemie der Universität Regensburg, Germany

Abstract

A novel supramolecular framework was obtained from the ligand H₂BDOA (benzene-1,3-dioxyacetic acid) that exhibited an SrAl₂ topology with 1.7 × 1.7 nm channels formed by strong hydrogen bonds and demonstrated an interesting crystal-to-crystal transformation property.

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Article information

DOI: https://doi.org/10.1039/B710389A
Article type: Communication
Submitted: 09 Jul 2007
Accepted: 06 Aug 2007
First published: 17 Aug 2007

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Chem. Commun., 2007, 4416-4418

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An unprecedented nanoporous and fluorescent supramolecular framework with an SrAl₂ topology controllably synthesized from a flexible ditopic acid

S. Wang, Y. Yang, J. Bai, Y. Li, M. Scheer, Y. Pan and X. You, Chem. Commun., 2007, 4416 DOI: 10.1039/B710389A

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Chemical Communications