Synthesis of AgBiS2 microspheres by a templating method and their catalytic polymerization of alkylsilanes

Jiaqiang Wang; Xikung Yang; Wenbing Hu; Bin Li; Jiangmei Yan; Jinjin Hu

doi:10.1039/B710832J

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Synthesis of AgBiS₂ microspheres by a templating method and their catalytic polymerization of alkylsilanes†

Jiaqiang Wang,*^a Xikung Yang,^b Wenbing Hu,^a Bin Li,^a Jiangmei Yan^a and Jinjin Hu^a

Author affiliations

* Corresponding authors

^a Department of Applied Chemistry, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunnan University, Kunming 650091, P. R. China
E-mail: jqwang@ynu.edu.cn
Fax: +86-871-5031567
Tel: +86-871-5031567

^b Research Center for Analysis and Measurement, Kunming University of Science and Technology, Kunming 650093, P. R. China

Abstract

AgBiS₂ microspheres synthesized by using PEG as a template serve as active catalysts for the polymerization of an alkylsilane, C₁₈H₃₇SiH₃ with water to form silanols.

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Supplementary files

Detailed preparation of AgBiS ₂ microspheres; characterizations; TEM of AgBiS ₂ microspheres and SEM images of the products of Bi ₂S ₃ microspheres incorporated with and without silver nanorods, and the mixture of AgBiS ₂?Bi ₂S ₃ microspheres with C ₁₈H ₃₇SiH ₃; O1s XPS spectra of as-synthesized products PDF (867K)

Article information

DOI: https://doi.org/10.1039/B710832J
Article type: Communication
Submitted: 16 Jul 2007
Accepted: 03 Sep 2007
First published: 19 Sep 2007

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Chem. Commun., 2007, 4931-4933

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Synthesis of AgBiS₂ microspheres by a templating method and their catalytic polymerization of alkylsilanes

J. Wang, X. Yang, W. Hu, B. Li, J. Yan and J. Hu, Chem. Commun., 2007, 4931 DOI: 10.1039/B710832J

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Chemical Communications