Issue 9, 2007
From the journal:

Dalton Transactions

Synthesis, characterization and propanemetathesis activity of a tantalum-hydride prepared on high surface area “silica supported zirconium hydroxide”†

Franck Rataboul,*a   Christophe Copéret,a   Laurent Lefort,a   Aimery de Mallmann,a   Jean Thivolle-Cazata  and  Jean-Marie Basset*a  

* Corresponding authors

a Laboratoire de Chimie Organométallique de Surface, CPE Lyon 43 Bd du 11 Novembre 1918, Villeurbanne Cedex, France
E-mail: basset@cpe.fr.

Abstract

A new tantalum–hydride supported on zirconium hydroxide [([triple bond, length as m-dash]SiO)2Zr(H)–O–Ta(H)x–(OSi[triple bond, length as m-dash])] (x = 1 or 3) was prepared using surface organometallic chemistry and its catalytic properties in the propane metathesis reaction were assessed showing improved activity and selectivities in comparison to the tantalum-hydride supported on silica.

Graphical abstract: Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area “silica supported zirconium hydroxide”

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Article information

DOI
https://doi.org/10.1039/B616921J
Article type
Paper
Submitted
20 Nov 2006
Accepted
04 Jan 2007
First published
18 Jan 2007

Dalton Trans., 2007, 923-927

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Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area “silica supported zirconium hydroxide”

F. Rataboul, C. Copéret, L. Lefort, A. de Mallmann, J. Thivolle-Cazat and J. Basset, Dalton Trans., 2007, 923 DOI: 10.1039/B616921J

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