Issue 25, 2007
From the journal:

Dalton Transactions

Organoruthenium derivative of the cyclic [H7P8W48O184]33− anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27−†‡

Sib Sankar Mal,a   Nadeen H. Nsouli,a   Michael H. Dickmana  and  Ulrich Kortz*a  

* Corresponding authors

a Jacobs University Bremen, School of Engineering and Science, P.O. Box 750 561, 28725 Bremen, Germany
E-mail: u.kortz@jacobs-university.de
Fax: +49-421-200 3229
Tel: +49-421-200 3235

Abstract

Reaction of [Ru(p-cymene)Cl2]2 with [H7P8W48O184]33− (P8W48) in aqueous acidic medium results in the organometallic derivative [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27− (1); in addition to the four {Ru(p-cymene)(H2O)} units, an unusual WO6 group with four equatorial, terminal ligands is also grafted to the crown-shaped P8W48 precursor.

Graphical abstract: Organoruthenium derivative of the cyclic [H7P8W48O184]33− anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27−

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Article information

DOI
https://doi.org/10.1039/B706762N
Article type
Communication
Submitted
04 May 2007
Accepted
11 May 2007
First published
21 May 2007

Dalton Trans., 2007, 2627-2630

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Organoruthenium derivative of the cyclic [H7P8W48O184]33− anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27−

S. S. Mal, N. H. Nsouli, M. H. Dickman and U. Kortz, Dalton Trans., 2007, 2627 DOI: 10.1039/B706762N

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