Issue 2, 2008
From the journal:

Chemical Communications

Using ionic liquids to trap unique coordination environments: polymorphic solvates of ErCl3(OH2)4·2([C2mim]Cl)

C. Corey Hines,a   Violina A. Cocalia†a  and  Robin D. Rogers*a  

* Corresponding authors

a Department of Chemistry and Center for Green Manufacturing, The University of Alabama, Tuscaloosa, AL, USA
E-mail: RDRogers@bama.ua.edu
Fax: 1 205 348 0823
Tel: 1 205 348 4323

Abstract

Two polymorphs of ErCl3(OH2)4·2([C2mim]Cl) solvates were isolated from the same solution of 1-ethyl-3-methylimidazolium chloride when HCl(aq) was added, while [C2mim]3[ErCl6] was isolated without HCl addition, illustrating how ionic liquids can be used to trap unusual coordination environments in the solid state.

Graphical abstract: Using ionic liquids to trap unique coordination environments: polymorphic solvates of ErCl3(OH2)4·2([C2mim]Cl)

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Article information

DOI
https://doi.org/10.1039/B711679A
Article type
Communication
Submitted
01 Aug 2007
Accepted
19 Oct 2007
First published
29 Oct 2007

Chem. Commun., 2008, 226-228

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Using ionic liquids to trap unique coordination environments: polymorphic solvates of ErCl3(OH2)4·2([C2mim]Cl)

C. C. Hines, V. A. Cocalia and R. D. Rogers, Chem. Commun., 2008, 226 DOI: 10.1039/B711679A

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